The conversion of meso-2,3-butanediol (1) into 2-butanol (3) by Lactobacillus brevis, via diol dehydratase-catalyzed reaction to 2-butanone (2), was shown to occur with complete discrimination between the two enantiomorphic-enantiotopic 1-hydroxyethyl groups of 1.
Evidence for enantiomorphic-enantiotopic group discrimination in diol dehydratase-catalyzed dehydration of meso-2,3-butanediol / G. Speranza, P. Manitto, G. Fontana, D. Monti, A. Galli. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 37:24(1996 Jun), pp. 4247-4250. [10.1016/0040-4039(96)00808-8]
Evidence for enantiomorphic-enantiotopic group discrimination in diol dehydratase-catalyzed dehydration of meso-2,3-butanediol
G. Speranza
Primo
;P. Manitto;A. GalliUltimo
1996
Abstract
The conversion of meso-2,3-butanediol (1) into 2-butanol (3) by Lactobacillus brevis, via diol dehydratase-catalyzed reaction to 2-butanone (2), was shown to occur with complete discrimination between the two enantiomorphic-enantiotopic 1-hydroxyethyl groups of 1.
File in questo prodotto:
| File | Dimensione | Formato | |
|---|---|---|---|
|
1-s2.0-0040403996008088-main.pdf
accesso riservato
Tipologia:
Publisher's version/PDF
Dimensione
220.62 kB
Formato
Adobe PDF
|
220.62 kB | Adobe PDF | Visualizza/Apri Richiedi una copia |
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
