The pre-disposal management of Radioactive Liquid Organic Waste (RLOW) is hampered by its challenging physico-chemical properties. In this work, a straightforward conditioning option based on RLOW impregnation on absorbing materials and followed by encapsulation in a stable geopolymeric matrix is proposed, avoiding onerous pre-treatments and the use of surfactants. Recycled materials have been investigated as adsorbent and geopolymer precursors to foster process sustainability. Relevant properties have been studied to ascertain the waste acceptance criteria accomplishment: materials compatibility, RLOW loading factor and bleeding, micro- structure, compressive strength, leaching and thermal stability. This approach is promising, although some criticalities remain unsolved

Pre-impregnation approach to encapsulate radioactive liquid organic waste in geopolymer / E. Mossini, A. Santi, G. Magugliani, F. Galluccio, E. Macerata, M. Giola, D. Vadivel, D. Dondi, D. Cori, P. Lotti, G.D. Gatta, M. Mariani. - In: JOURNAL OF NUCLEAR MATERIALS. - ISSN 0022-3115. - 585:(2023 Nov), pp. 154608.1-154608.9. [10.1016/j.jnucmat.2023.154608]

Pre-impregnation approach to encapsulate radioactive liquid organic waste in geopolymer

P. Lotti
Writing – Review & Editing
;
G.D. Gatta
Penultimo
Writing – Review & Editing
;
2023

Abstract

The pre-disposal management of Radioactive Liquid Organic Waste (RLOW) is hampered by its challenging physico-chemical properties. In this work, a straightforward conditioning option based on RLOW impregnation on absorbing materials and followed by encapsulation in a stable geopolymeric matrix is proposed, avoiding onerous pre-treatments and the use of surfactants. Recycled materials have been investigated as adsorbent and geopolymer precursors to foster process sustainability. Relevant properties have been studied to ascertain the waste acceptance criteria accomplishment: materials compatibility, RLOW loading factor and bleeding, micro- structure, compressive strength, leaching and thermal stability. This approach is promising, although some criticalities remain unsolved
Radioactive liquid organic waste; Recycled polyurethane; Pre-impregnation; Geopolymer; Waste acceptance criteria
Settore GEO/09 - Georisorse Miner.Appl.Mineral.-Petrogr.per l'amb.e i Beni Cul
   PRE-DISposal management of radioactive waste
   PREDIS
   European Commission
   Horizon 2020 Framework Programme
   945098

   Assegnazione Dipartimenti di Eccellenza 2023-2027 - Dipartimento di SCIENZE DELLA TERRA "ARDITO DESIO"
   DECC23_020
   MINISTERO DELL'UNIVERSITA' E DELLA RICERCA
nov-2023
6-lug-2023
https://www.sciencedirect.com/science/article/pii/S0022311523003756?via=ihub
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/984528
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