A new photoactive material was obtained by the heterogenization of zinc(II) porphyrin onto cellulose-based Colour Catcher® sheet. The so-obtained Zn(porphyrin)@CC material performed very well in activating molecular oxygen in the photooxidative coupling of amines to imines and the photooxidation of aldehydes to corresponding acids in the presence of white light. The high eco-compatibility of the solid support, the chemical stability of the photoactive material and the mild experimental conditions applied confer a very good sustainability to the procedure and open the doors to a larger employment of Colour Catcher®-based porphyrin material in reactions mediated by light.

Porphyrins Anchored onto Colour Catcher®: Photoactive Material for the Conversion of Amines into Imines and Aldehydes into Carboxylic Acids / C. Damiano, M. Cavalleri, C. di Natale', R. Paolesse, E. Gallo. - In: CHEMISTRYEUROPE. - ISSN 2751-4765. - (2023), pp. 1-10. [Epub ahead of print] [10.1002/ceur.202300020]

Porphyrins Anchored onto Colour Catcher®: Photoactive Material for the Conversion of Amines into Imines and Aldehydes into Carboxylic Acids

C. Damiano
Primo
;
M. Cavalleri
Secondo
;
E. Gallo
Ultimo
2023

Abstract

A new photoactive material was obtained by the heterogenization of zinc(II) porphyrin onto cellulose-based Colour Catcher® sheet. The so-obtained Zn(porphyrin)@CC material performed very well in activating molecular oxygen in the photooxidative coupling of amines to imines and the photooxidation of aldehydes to corresponding acids in the presence of white light. The high eco-compatibility of the solid support, the chemical stability of the photoactive material and the mild experimental conditions applied confer a very good sustainability to the procedure and open the doors to a larger employment of Colour Catcher®-based porphyrin material in reactions mediated by light.
Settore CHIM/03 - Chimica Generale e Inorganica
   Piano di Sostegno alla Ricerca 2015-2017 - Linea 2 "Dotazione annuale per attività istituzionali" (anno 2020)
   UNIVERSITA' DEGLI STUDI DI MILANO
2023
5-mag-2023
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/969008
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