A redox umpolung strategy for the synthesis of complex tetrahydrocarbazoles is reported. The reaction involves a visible light promoted radical cation [4+2] cycloaddition between 2-vinylindoles and conjugated alkenes that proceeds with good yields and diastereoselectivity.
Synthesis of tetrahydrocarbazoles through a radical cation [4+2] cycloaddition reaction of 2-vinylindoles / E. Brambilla, E. Moretti, M. Magni, G. Abbiati, V. Pirovano. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - (2023), pp. 1-4. [Epub ahead of print] [10.1039/D2CC06723D]
Synthesis of tetrahydrocarbazoles through a radical cation [4+2] cycloaddition reaction of 2-vinylindoles
E. BrambillaPrimo
;M. Magni;G. AbbiatiPenultimo
;V. Pirovano
Ultimo
2023
Abstract
A redox umpolung strategy for the synthesis of complex tetrahydrocarbazoles is reported. The reaction involves a visible light promoted radical cation [4+2] cycloaddition between 2-vinylindoles and conjugated alkenes that proceeds with good yields and diastereoselectivity.
File in questo prodotto:
| File | Dimensione | Formato | |
|---|---|---|---|
|
d2cc06723d-2.pdf
accesso aperto
Tipologia:
Publisher's version/PDF
Dimensione
950.54 kB
Formato
Adobe PDF
|
950.54 kB | Adobe PDF | Visualizza/Apri |
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
