The use of phenyl formate as a carbon Monoxide surrogate in reductive cyclization of nitrobiphenyls catalyzed by palladium/phenanthroline complexes has been investigated and the reaction conditions optimized. The best conditions have been applied to the synthesis of several carbazoles in good to excellent yields.
Carbon Monoxide surrogates in the Synthesis of Heterocycles: Reductive Cyclization of Nitrobiphenyls Catalyzed by Palladium/Phenanthroline Complexes / F. Ferretti, M. Abdellatif, F. Ragaini. ((Intervento presentato al 44. convegno International Conference on Coordination Chemistry (ICCC2022) tenutosi a Rimini nel 2022.
Carbon Monoxide surrogates in the Synthesis of Heterocycles: Reductive Cyclization of Nitrobiphenyls Catalyzed by Palladium/Phenanthroline Complexes
F. FerrettiPrimo
;M. Abdellatif;F. Ragaini
2022
Abstract
The use of phenyl formate as a carbon Monoxide surrogate in reductive cyclization of nitrobiphenyls catalyzed by palladium/phenanthroline complexes has been investigated and the reaction conditions optimized. The best conditions have been applied to the synthesis of several carbazoles in good to excellent yields.
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