The synthesis of phosphorus-rich analogues of carbon-based compounds is a desirable but challenging endeavour. Now, the synthesis of the anion [Fe(P4)2]2– is reported, which so far is the most similar all-phosphorus relative to well-known ferrocene, [Fe(η5-C5H5)2].
Phosphorus makes inroads / T. Grell, E. Hey-Hawkins. - In: NATURE SYNTHESIS. - ISSN 2731-0582. - 1:6(2022 May 31), pp. 422-423. [10.1038/s44160-022-00090-9]
Phosphorus makes inroads
T. GrellPrimo
;
2022
Abstract
The synthesis of phosphorus-rich analogues of carbon-based compounds is a desirable but challenging endeavour. Now, the synthesis of the anion [Fe(P4)2]2– is reported, which so far is the most similar all-phosphorus relative to well-known ferrocene, [Fe(η5-C5H5)2].File in questo prodotto:
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