In this issue of Chem Catalysis, Wang et al. report the synthesis of 1,1-cyclopropanediesters promoted by a D2-symmetric chiral amidoporphyrin catalyst. The carbene transfer from unsymmetrical diazomalonates to a large scope of challenging alkenes occurred with high stereocontrol thanks to the efficiency of Co(II)-based metalloradical catalytic system.
Challenging asymmetric alkene cyclopropanation by unsymmetrical diazomalonates / C. Damiano, E. Gallo. - In: CHEM CATALYSIS. - ISSN 2667-1093. - 2:2(2022 Feb 17), pp. 229-231. [10.1016/j.checat.2022.01.006]
Challenging asymmetric alkene cyclopropanation by unsymmetrical diazomalonates
C. DamianoPrimo
;E. Gallo
Ultimo
2022
Abstract
In this issue of Chem Catalysis, Wang et al. report the synthesis of 1,1-cyclopropanediesters promoted by a D2-symmetric chiral amidoporphyrin catalyst. The carbene transfer from unsymmetrical diazomalonates to a large scope of challenging alkenes occurred with high stereocontrol thanks to the efficiency of Co(II)-based metalloradical catalytic system.
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