Etruscan Fine Ware Pottery: Near-Infrared ({NIR}) Spectroscopy as a Tool for the Investigation of Clay Firing Temperature and Atmosphere

Fine ware pottery from the Etruscan town of Tarquinia, whose necropolis in inscribed in the list of UNESCO sites, was studied by means of near-infrared (NIR) diffuse reflection spectroscopy. The aim was to investigate the correlation between the firing conditions of the illitic-calcareous local clay, in terms of temperature and atmosphere, and the physical properties of the ceramic paste, usually exploited by the archaeologists for a classification of pottery sherds. For comparison, analytical data related to the mineralogical composition of the samples were obtained by X-ray diffraction and Fourier-transform infrared (FTIR) spectroscopy. Spectroscopic data were elaborated by methods of multivariate analysis.