Nickel (0) Complexes as Promising Chemosensors for Detecting the “Cork Taint” in Wine

2,4,6-Trichloroanisole (TCA) is well recognized as one of the most responsible molecules of cork taint, an organoleptic defect of wine which represents a serious problem for wine industries. Up to now, very few examples of TCA-biosensors have been developed and we report herein a promising nickel (0) complex that can be employed as chemosensor for the TCA detection in cork stoppers. Among the three Ni (0) complexes studied in this work, complex Ni(0)(BINAP)(eta(2)-PhCN) (2) showed the best reactivity towards pure TCA affording the oxidative addition product 4 in four hours at room temperature. Compound 4 represents an appealing probe for the indirect quantification of TCA due to the presence of the characteristic UV-adsorption band at 444 nm. Statistical studies on real samples confirmed that the presence of TCA can be detected by employing UV-Visible spectroscopy, as demonstrated by PCA analyses which allowed distinguishing TCA-contaminated samples from non-contaminated ones. Even if the present study has to be considered a preliminary approach for the realization of a chemosensor usable in real systems, the here reported Ni (0)-based sensing procedure represents the first examples of TCA chemical detection.