Melt–rock interactions in a veined mantle: pyroxenite–peridotite reaction experiments at 2 GPa

Interaction between peridotite and pyroxenite-derived melts can significantly modify the mineralogy and chemistry of the upper mantle, enhancing its heterogeneity, by creating re-fertilized peridotites and secondary-type pyroxenites. We experimentally investigated the reaction between a fertile lherzolite and MgOrich basaltic andesite produced by partial melting of an olivine-free pyroxenite at 2 GPa and 1300-1450 degrees C. The aim was to constrain the rate and style of melt-peridotite reaction mostly as a function of temperature, i.e. assuming variable physical status of the host peridotite. Experiments juxtaposed pyroxenite on a synthesized fertile lherzolite to evaluate the modal and mineral compositional changes in the fertile lherzolite resulting from the reaction with pyroxenite-derived melt. At 1300 and 1350 degrees C, the reaction produces a thin orthopyroxenerich reaction zone confined between partially molten pyroxenite and modally unmodified subsolidus lherzolite. Chemical changes in minerals of the pyroxenite crystal mush suggest that element diffusion across the pyroxenite-peridotite interface, coupled with orthopyroxene precipitation, plays a role in the reactive crystallization of mantle pyroxenite veins. At 1380 and 1400 degrees C, infiltration of pyroxenite-derived melt significantly modifies the mineralogy and chemistry of the host peridotite by creating orthopyroxene-rich websterites and pyroxene-rich lherzolite. At 1450 degrees C, pyroxenitic melt fluxes into molten peridotite, enhancing peridotite melting and creating a melt-bearing dunite associated with a refractory harzburgite. At a given pressure, bulk compositions of hybrid rocks originating through melt-peridotite interaction are mostly controlled by the chemistry of the reacting melt. Interaction between pyroxenitic melt and peridotite causes X-Mg[X-Mg = Mg/(Mg + Fe-tot /U and X-Cr[X-Cr = Cr/(Cr + Al)] decrease and TiO2 increase in pyroxenes and spinel across the pyroxenite-peridotite boundary. Similar chemical gradients in minerals are observed in pyroxenite-peridotite associations from natural mantle sequences. The comparison with mineral chemistry variations derived by reaction experiments potentially represents a petrologic tool to discriminate between low- versus high-temperature melt-peridotite reactions.