The reaction of [Na2(thf)4P4Mes4] (1) (Mes = 2,4,6-Me3C6H2) with 1,3-dimethylimidazolin-2-ylidene (Me2Im) or the corresponding imidazolium iodide ([Me2ImH]I) leads to P-P bond cleavage and formation of the carbene-phosphinidene adduct (Me2Im)PMes (2), which was characterized by NMR spectroscopy, mass spectrometry, and X-ray crystallography.
Formation of a Carbene-Phosphinidene Adduct by NHC-Induced P-P Bond Cleavage in Sodium Tetramesityltetraphosphanediide / A.K. Adhikari, T. Grell, P. Lonnecke, E. Hey-Hawkins. - In: EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. - ISSN 1434-1948. - 2016:5(2016 Feb), pp. 620-622. [10.1002/ejic.201500952]
Formation of a Carbene-Phosphinidene Adduct by NHC-Induced P-P Bond Cleavage in Sodium Tetramesityltetraphosphanediide
T. Grell;
2016
Abstract
The reaction of [Na2(thf)4P4Mes4] (1) (Mes = 2,4,6-Me3C6H2) with 1,3-dimethylimidazolin-2-ylidene (Me2Im) or the corresponding imidazolium iodide ([Me2ImH]I) leads to P-P bond cleavage and formation of the carbene-phosphinidene adduct (Me2Im)PMes (2), which was characterized by NMR spectroscopy, mass spectrometry, and X-ray crystallography.
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