Tris(pentafluorophenyl)silanol (C6F5)3SiOH was prepared from the corresponding chlorosilane (C6F5)3SiCl by an unconventional controlled hydrolysis. The X-ray structure and the reactivity of the new silanol with various bases, with triflic acid and with some rhenium carbonyl complexes are reported. The Si-C6F5 bond is easily cleaved in the presence of even weak bases and this behaviour prevented the isolation of the (C6F5)3SiO- anion and the synthesis of the [Re(CO)5COSiR3] derivative. In particular, when (C6F5)3SiOH was reacted with butyllithium and Re(CO)5OSO2CF3 the formation of [Re(CO)5C6F5] was observed.
Synthesis, reactivity and X-ray crystal structure of tris(pentafluorophenyl) silanol (C6F5)3SiOH / T. Giovenzana, E. Lucenti, L. Carlucci, G. D’Alfonso, D. Maggioni, A. Sironi, E. Cariati. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - 353(2022 Apr 01), pp. 120778.1-120778.9. [10.1016/j.ica.2021.120778]
Synthesis, reactivity and X-ray crystal structure of tris(pentafluorophenyl) silanol (C6F5)3SiOH
L. Carlucci;D. Maggioni;E. Cariati
Ultimo
2022
Abstract
Tris(pentafluorophenyl)silanol (C6F5)3SiOH was prepared from the corresponding chlorosilane (C6F5)3SiCl by an unconventional controlled hydrolysis. The X-ray structure and the reactivity of the new silanol with various bases, with triflic acid and with some rhenium carbonyl complexes are reported. The Si-C6F5 bond is easily cleaved in the presence of even weak bases and this behaviour prevented the isolation of the (C6F5)3SiO- anion and the synthesis of the [Re(CO)5COSiR3] derivative. In particular, when (C6F5)3SiOH was reacted with butyllithium and Re(CO)5OSO2CF3 the formation of [Re(CO)5C6F5] was observed.File | Dimensione | Formato | |
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