Lithium halocarbenoids are versatile reagents for accomplishing homologation processes. The fast α-elimination they suffer has been considered an important limitation for their extensive use. Herein, we present a series of practical considerations for an effective employment in the homologation of selected carbon electrophiles. Graphical abstract: [Figure not available: see fulltext.].
A practical guide for using lithium halocarbenoids in homologation reactions / S. Monticelli, M. Rui, L. Castoldi, G. Missere, V. Pace. - In: MONATSHEFTE FÜR CHEMIE. - ISSN 0026-9247. - 149:7(2018 Jul), pp. 1285-1291. [10.1007/s00706-018-2232-9]
A practical guide for using lithium halocarbenoids in homologation reactions
L. Castoldi;
2018
Abstract
Lithium halocarbenoids are versatile reagents for accomplishing homologation processes. The fast α-elimination they suffer has been considered an important limitation for their extensive use. Herein, we present a series of practical considerations for an effective employment in the homologation of selected carbon electrophiles. Graphical abstract: [Figure not available: see fulltext.].
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