Lithium halocarbenoids are versatile reagents for accomplishing homologation processes. The fast α-elimination they suffer has been considered an important limitation for their extensive use. Herein, we present a series of practical considerations for an effective employment in the homologation of selected carbon electrophiles. Graphical abstract: [Figure not available: see fulltext.].

A practical guide for using lithium halocarbenoids in homologation reactions / S. Monticelli, M. Rui, L. Castoldi, G. Missere, V. Pace. - In: MONATSHEFTE FÜR CHEMIE. - ISSN 0026-9247. - 149:7(2018 Jul), pp. 1285-1291. [10.1007/s00706-018-2232-9]

A practical guide for using lithium halocarbenoids in homologation reactions

L. Castoldi;
2018

Abstract

Lithium halocarbenoids are versatile reagents for accomplishing homologation processes. The fast α-elimination they suffer has been considered an important limitation for their extensive use. Herein, we present a series of practical considerations for an effective employment in the homologation of selected carbon electrophiles. Graphical abstract: [Figure not available: see fulltext.].
Carbenoids; Lithiation; Organometallics
Settore CHIM/06 - Chimica Organica
11-giu-2018
Article (author)
File in questo prodotto:
File Dimensione Formato  
Monticelli2018_Article_APracticalGuideForUsingLithium(1).pdf

accesso aperto

Tipologia: Publisher's version/PDF
Dimensione 899.99 kB
Formato Adobe PDF
899.99 kB Adobe PDF Visualizza/Apri
Pubblicazioni consigliate

Caricamento pubblicazioni consigliate

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/890723
Citazioni
  • ???jsp.display-item.citation.pmc??? 0
  • Scopus 4
  • ???jsp.display-item.citation.isi??? 4
social impact