Selective Formation of a Supramolecular Coordination Complex in the Nanometre Scale with a Ferrocene-based Phospholane Ligand

A straightforward synthesis of the tetradentate phospholane ligand 1 is reported. The 2 : 1 [M : L] reaction of 1 with [AuCl(tht)] (tht = tetrahydrothiophene) resulted in the 4 : 2 [M : L] supramolecular coordination complex 2 where two ligands 1 are bridging four gold(i) cations. The formation of 2 can be rationalised via a geometrical analysis of the ligand. The coordination mode of the gold atoms was evaluated based on a CSD search, revealing the geometrical changes for a transition from linear to trigonal planar coordination environment.