The stereoselective organocatalytic addition of silyl enol ethers to aromatic aldehydes catalyzed by bisphosphoramides and the direct aldol reaction between ketones and aromatic aldehydes promoted by phosphinoxides in the presence of tetrachlorosilane were investigated by the DFT approach. The formation of different chiral cationic hypervalent silicon species was investigated by calculations. Investigation on Lewis base catalyzed Lewis acid mediated cross aldol reactions was also performed.
DFT investigation on Lewis base-catalyzed Lewis acid-mediated reactions: Hypervalent silicon species as chiral organocatalysts in (direct) aldol reactions / S. Rossi, M. Benaglia, L.M. Raimondi. - In: NEW JOURNAL OF CHEMISTRY. - ISSN 1144-0546. - 44:44(2020 Nov 28), pp. 19288-19293.
|Titolo:||DFT investigation on Lewis base-catalyzed Lewis acid-mediated reactions: Hypervalent silicon species as chiral organocatalysts in (direct) aldol reactions|
ROSSI, SERGIO (Primo) (Corresponding)
BENAGLIA, MAURIZIO (Secondo)
RAIMONDI, LAURA MARIA (Ultimo)
|Settore Scientifico Disciplinare:||Settore CHIM/06 - Chimica Organica|
|Progetto:||PIANO DI SOSTEGNO ALLA RICERCA 2015-2017 - LINEA 2 "DOTAZIONE ANNUALE PER ATTIVITA' ISTITUZIONALE"|
|Data di pubblicazione:||28-nov-2020|
|Data ahead of print / Data di stampa:||15-ott-2020|
|Digital Object Identifier (DOI):||http://dx.doi.org/10.1039/d0nj03976d|
|Appare nelle tipologie:||01 - Articolo su periodico|