We review recent experimental data obtained with quasi-one-dimensional (1D) molecular magnets Gd(hfaC)(3)NITR. For Gd(hfac)(3)NITiPr the results can be coherently explained only in terms of the Villain's conjecture: a chiral order at intermediate temperatures and helical order at low temperatures. In the case of weakly frustrated molecular magnetic chain compounds Gd(hfac)(3)-NITPh, new specific heat measurements show the presence of a phase transition to the three-dimensional (3D) helical order, observed at T similar to 0.63 K. In the temperature range 25-250 mK the experimental specific heat data are reproduced very well by a simple spin wave theory.
Chiral and helical phase transitions in quasi-1D molecular magnets / F. Cinti, M. Affronte, A. Lascialfari, M. Barucci, E. Olivieri, E. Pasca, A. Rettori, L. Risegari, G. Ventura, M.G. Pini, A. Cuccoli, T. Roscilde, A. Caneschi, D. Gatteschi, D. Rovai. - In: POLYHEDRON. - ISSN 0277-5387. - 24:16-17(2005), pp. 2568-2572. [10.1016/j.poly.2005.03.124]
Chiral and helical phase transitions in quasi-1D molecular magnets
A. Lascialfari;
2005
Abstract
We review recent experimental data obtained with quasi-one-dimensional (1D) molecular magnets Gd(hfaC)(3)NITR. For Gd(hfac)(3)NITiPr the results can be coherently explained only in terms of the Villain's conjecture: a chiral order at intermediate temperatures and helical order at low temperatures. In the case of weakly frustrated molecular magnetic chain compounds Gd(hfac)(3)-NITPh, new specific heat measurements show the presence of a phase transition to the three-dimensional (3D) helical order, observed at T similar to 0.63 K. In the temperature range 25-250 mK the experimental specific heat data are reproduced very well by a simple spin wave theory.
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
