The supramolecular assembly containing an electron donor, zinc 5,10,15,20-meso-tetraferrocenylporphyrin, and a pyridine-substituted fulleropyrrolidine as an electron acceptor, has been investigated. A comparison of the photophysical properties of the separate components and of the assembled system revealed a photoinduced electron-transfer process from the porphyrin to the fullerene unit. Time-resolved spectroscopy, on the subpicosecond time scale, was performed to determine the rate of the forward and back electron-transfer reactions.
Zinc 5,10,15,20-meso-tetraferrocenylporphyrin as an efficient donor in a supramolecular fullerene C60 system / P. Galloni, B. Floris, L. De Cola, E. Cecchetto, R.M. Williams. - In: JOURNAL OF PHYSICAL CHEMISTRY. C. - ISSN 1932-7447. - 111:3(2007), pp. 1517-1523. [10.1021/jp064307h]
Zinc 5,10,15,20-meso-tetraferrocenylporphyrin as an efficient donor in a supramolecular fullerene C60 system
L. De Cola;
2007
Abstract
The supramolecular assembly containing an electron donor, zinc 5,10,15,20-meso-tetraferrocenylporphyrin, and a pyridine-substituted fulleropyrrolidine as an electron acceptor, has been investigated. A comparison of the photophysical properties of the separate components and of the assembled system revealed a photoinduced electron-transfer process from the porphyrin to the fullerene unit. Time-resolved spectroscopy, on the subpicosecond time scale, was performed to determine the rate of the forward and back electron-transfer reactions.
| File | Dimensione | Formato | |
|---|---|---|---|
|
jp064307h.pdf
accesso riservato
Tipologia:
Publisher's version/PDF
Dimensione
253.15 kB
Formato
Adobe PDF
|
253.15 kB | Adobe PDF | Visualizza/Apri Richiedi una copia |
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
