Chemecal quation Reprsent Sticking together: The pore entrances of dye-loaded green or red zeolite L crystals can be site-specifically modified with either alkoxyamines or nitroxide radicals. Mild radical nitroxide exchange reactions of alkoxyamine-terminated "green" zeolite crystals with nitroxide-terminated "red" crystals leads to highly regular crystal chains that contain up to 15 covalently connected crystals with strictly alternating colors.
Dynamic microcrystal assembly by nitroxide exchange reactions / B. Schulte, M. Tsotsalas, M. Becker, A. Studer, L. De Cola. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - 49:38(2010), pp. 6881-6884. [10.1002/anie.201002851]
Dynamic microcrystal assembly by nitroxide exchange reactions
L. De Cola
2010
Abstract
Chemecal quation Reprsent Sticking together: The pore entrances of dye-loaded green or red zeolite L crystals can be site-specifically modified with either alkoxyamines or nitroxide radicals. Mild radical nitroxide exchange reactions of alkoxyamine-terminated "green" zeolite crystals with nitroxide-terminated "red" crystals leads to highly regular crystal chains that contain up to 15 covalently connected crystals with strictly alternating colors.
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