Functionalization of amorphous SiO 2 and 6H-SiC(0001) surfaces with benzo[ghi]perylene-1,2-dicarboxylic anhydride via an APTES linker

The successful covalent functionalization of quartz and n-type 6H-SiC with organosilanes and benzo[ghi]perylene-1,2-dicarboxylic dye is demonstrated. In particular, wet-chemically processed self-assembled layers of aminopropyltriethoxysilane (APTES) and benzo[ghi]perylene-1,2-dicarboxylic anhydride are investigated. The structural and chemical properties of these layers are studied by contact angle measurements, attenuated total reflection infrared (ATR-IR) spectroscopy, and X-ray photoelectron spectroscopy (XPS). The optical properties are measured by confocal microscopy. The wetting angles observed for the organic layers are α = 68° for the APTES-functionalized surface, while angles of α = 85°and 78°are determined for dye-functionalized quartz and 6H-SiC surfaces, respectively. However, not all amino groups of the APTES-functionalized surfaces react to bind dye molecules. Further dye functionalization is not uniform throughout the surface, showing different island sizes of the dye and including different chemical environments. The quartz surface exhibits a higher packing density of dyes than the 6H-SiC surface. The fluorescence lifetimes of the surface-attached dye show double exponential decays of about 1.4 and 4.2 ns, largely independent of the substrates. Functionalization of SiC with a fluorescent dye is achieved in two steps. On the hydroxyl-terminated substrate, a silanization reaction first covalenty binds a 3-aminopropyl triethoxysilane (APTES) linker molecule at which the perylene dye is subsequently attached. Spatially resolved fluorescence lifetime measurements indicate that the dye is electronically isolated from the substrate. Furthermore, the formation of H-H complexes is observed.