The solvent-assisted self-assembly of a blue-emitting neutral platinum(ii) complex into micrometer-long and highly crystalline fibers has been achieved. The aggregates show highly efficient (quantum yield up to 74%) polarized yellow-orange light emission, as a consequence of their high degree of supramolecular order imparted by weak non-covalent intermolecular (metal⋯metal and π–π) interactions.
Self-assembly of a neutral platinum(ii) complex into highly emitting microcrystalline fibers through metallophilic interactions / M. Mauro, A. Aliprandi, C. Cebrian, D. Wang, C. Kubel, L. De Cola. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 50:55(2014), pp. 7269-7272. [10.1039/c4cc01045k]
Self-assembly of a neutral platinum(ii) complex into highly emitting microcrystalline fibers through metallophilic interactions
L. De Cola
2014
Abstract
The solvent-assisted self-assembly of a blue-emitting neutral platinum(ii) complex into micrometer-long and highly crystalline fibers has been achieved. The aggregates show highly efficient (quantum yield up to 74%) polarized yellow-orange light emission, as a consequence of their high degree of supramolecular order imparted by weak non-covalent intermolecular (metal⋯metal and π–π) interactions.
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