A high yield synthetic route for the preparation of N-6 coordinated heteroleptic Ir(III) complexes using bidentate polypyridyl type ligands is described. The complexes are near-blue emitters and showmicrosecond emission lifetimes, high emission quantum yields and have two quasi-reversible reduction processes between -1.0 and -1.3 V vs. Ag/AgCl.
New synthetic pathways to the preparation of near-blue emitting heteroleptic Ir(III)N6 coordinated compounds with microsecond lifetimes / S. Soman, J.C. Manton, J.L. Inglis, Y. Halpin, B. Twamley, E. Otten, W.R. Browne, L. De Cola, J.G. Vos, M.T. Pryce. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 50:49(2014), pp. 6461-6463. [10.1039/c4cc02249a]
New synthetic pathways to the preparation of near-blue emitting heteroleptic Ir(III)N6 coordinated compounds with microsecond lifetimes
L. De Cola;
2014
Abstract
A high yield synthetic route for the preparation of N-6 coordinated heteroleptic Ir(III) complexes using bidentate polypyridyl type ligands is described. The complexes are near-blue emitters and showmicrosecond emission lifetimes, high emission quantum yields and have two quasi-reversible reduction processes between -1.0 and -1.3 V vs. Ag/AgCl.
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