Primary alcohols containing at the α-carbon small groups such as methyl or an oxirane ring are efficiently and with high enantioselectivity resolved by an irreversible transesterification reaction with vinyl acetate in chloroform or dichloromethane, catalyzed by a lipase from Pseudomonas fluorescens.
α-substituted primary alcohols as substrates for enantioselective lipase-catalyzed transesterification in organic solvents / E. Santaniello, P. Ferraboschi, P. Grisenti, A. Manzocchi (PROGRESS IN BIOTECHNOLOGY). - In: Progress in Biotechnology[s.l] : elsevier, 1992. - ISBN 9780444890467. - pp. 533-540
α-substituted primary alcohols as substrates for enantioselective lipase-catalyzed transesterification in organic solvents
E. Santaniello;P. Ferraboschi;A. Manzocchi
1992
Abstract
Primary alcohols containing at the α-carbon small groups such as methyl or an oxirane ring are efficiently and with high enantioselectivity resolved by an irreversible transesterification reaction with vinyl acetate in chloroform or dichloromethane, catalyzed by a lipase from Pseudomonas fluorescens.
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