Enantiomerically pure (R)- and (S)-epoxyalcohols 1, chiral intermediates for the synthesis of (R)- and (S)-frontalin 2, are prepared by Pseudomonas fluorescens lipase-catalyzed transesterification in dichloromethane.

A chemoenzymatic approach to enantiomerically pure (R)- and (S)-2,3-epoxy-2-(4-pentenyl)-propanol, a chiral building block for the synthesis of (R)- and (S)-frontalin / P. Ferraboschi, S. Casati, P. Grisenti, E. Santaniello. - In: TETRAHEDRON-ASYMMETRY. - ISSN 0957-4166. - 4:1(1993), pp. 9-12. [10.1016/S0957-4166(00)86004-8]

A chemoenzymatic approach to enantiomerically pure (R)- and (S)-2,3-epoxy-2-(4-pentenyl)-propanol, a chiral building block for the synthesis of (R)- and (S)-frontalin

P. Ferraboschi
Primo
;
S. Casati
Secondo
;
E. Santaniello
Ultimo
1993

Abstract

Enantiomerically pure (R)- and (S)-epoxyalcohols 1, chiral intermediates for the synthesis of (R)- and (S)-frontalin 2, are prepared by Pseudomonas fluorescens lipase-catalyzed transesterification in dichloromethane.
asymmetric epoxidation; organic-synthesis; bakers-yeast; ester; (-)-frontalin; frontalin; alcohols; (S)-(-)-frontalin; resolution; alkylation
Settore BIO/10 - Biochimica
1993
Article (author)
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/761513
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