Whereas there is an increasing amount of reports on the second-order nonlinear optical (NLO) and luminescence properties of tetradentate [N2O2] Schiff base-zinc complexes, the study of zinc complexes having two bidentate [NO] Schiff-base ligands is relatively unexplored from an NLO point of view. This work puts in evidence that the known chiral bis(2-[(R)-(+)-1-phenylethyliminomethyl]phenolato-N, O)zinc(II) complex is a fascinating multifunctional molecular inorganic-organic hybrid material characterized by interesting second-order NLO and luminescent properties in solution. The emissive properties of the organic 2-(R)-(+)-1-phenylethyliminomethyl]phenol proligand are greatly enhanced upon coordination to the inorganic Zn(II) center.

A chiral bis(salicylaldiminato)zinc(ii) complex with second-order nonlinear optical and luminescent properties in solution / P. Matozzo, A. Colombo, C. Dragonetti, S. Righetto, D. Roberto, P. Biagini, S. Fantacci, D. Marinotto. - In: INORGANICS. - ISSN 2304-6740. - 8:4(2020).

A chiral bis(salicylaldiminato)zinc(ii) complex with second-order nonlinear optical and luminescent properties in solution

A. Colombo
Secondo
;
C. Dragonetti;S. Righetto;D. Roberto
;
D. Marinotto
Ultimo
2020

Abstract

Whereas there is an increasing amount of reports on the second-order nonlinear optical (NLO) and luminescence properties of tetradentate [N2O2] Schiff base-zinc complexes, the study of zinc complexes having two bidentate [NO] Schiff-base ligands is relatively unexplored from an NLO point of view. This work puts in evidence that the known chiral bis(2-[(R)-(+)-1-phenylethyliminomethyl]phenolato-N, O)zinc(II) complex is a fascinating multifunctional molecular inorganic-organic hybrid material characterized by interesting second-order NLO and luminescent properties in solution. The emissive properties of the organic 2-(R)-(+)-1-phenylethyliminomethyl]phenol proligand are greatly enhanced upon coordination to the inorganic Zn(II) center.
EFISH; Luminescence; Second-order nonlinear optics; Zinc(II) complexes
Settore CHIM/03 - Chimica Generale e Inorganica
2020
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/741907
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