Edge-transitive and related minimal transitivity nets play a central role in the designed synthesis of crystalline framework materials (reticular chemistry), in particular, metal− organic frameworks. We report a new family of 13 edge-transitive nets that have previously gone unidentified theoretically and their associated minimal transitivity nets. Their relevance to existed materials is noted, uncovering new nets with minimal transitivity 3 2 (three kinds of nodes and two kinds of edges), mostly never known or observed in real crystals, for future design.

A New Group of Edge-transitive 3-Periodic Nets and Their Derived Nets for Reticular Chemistry / M. Li, M. O’Keeffe, D.M. Proserpio, H. Zhang. - In: CRYSTAL GROWTH & DESIGN. - ISSN 1528-7483. - 20:6(2020 Jun 03), pp. 4062-4068. [10.1021/acs.cgd.0c00275]

A New Group of Edge-transitive 3-Periodic Nets and Their Derived Nets for Reticular Chemistry

D.M. Proserpio
Penultimo
;
2020

Abstract

Edge-transitive and related minimal transitivity nets play a central role in the designed synthesis of crystalline framework materials (reticular chemistry), in particular, metal− organic frameworks. We report a new family of 13 edge-transitive nets that have previously gone unidentified theoretically and their associated minimal transitivity nets. Their relevance to existed materials is noted, uncovering new nets with minimal transitivity 3 2 (three kinds of nodes and two kinds of edges), mostly never known or observed in real crystals, for future design.
edge-transitive net; metal organic frameworks; reticular chemistry
Settore CHIM/03 - Chimica Generale e Inorganica
   PIANO DI SOSTEGNO ALLA RICERCA 2015-2017 - TRANSITION GRANT LINEA 1A PROGETTO "UNIMI PARTENARIATI H2020"
   UNIVERSITA' DEGLI STUDI DI MILANO
3-giu-2020
28-apr-2020
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/741553
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