Sakurai and Mukaiyama aldol reactions have been studied using (tetraMeBITIOP)silver(I) and (BITIANP)silver(I) complexes as catalysts; these complexes show high and comparable activities despite the differences in the electron availability and Lewis acid character of the phosphorus atoms.

Enantioselective Mukaiyama aldol and Sakurai allylation reactions catalysed by silver(I) complexes with chiral atropisomeric chelating ligands / E. Cesarotti, S. Araneo, I. Rimoldi, S. Tassi. - In: JOURNAL OF MOLECULAR CATALYSIS. A: CHEMICAL. - ISSN 1381-1169. - 204-205(2003), pp. 221-226.

Enantioselective Mukaiyama aldol and Sakurai allylation reactions catalysed by silver(I) complexes with chiral atropisomeric chelating ligands

E. Cesarotti;S. Araneo;I. Rimoldi;
2003

Abstract

Sakurai and Mukaiyama aldol reactions have been studied using (tetraMeBITIOP)silver(I) and (BITIANP)silver(I) complexes as catalysts; these complexes show high and comparable activities despite the differences in the electron availability and Lewis acid character of the phosphorus atoms.
chiral Lewis acid; mukaiyama reaction; sakurai reaction; TetraMeBITIOP; BITIANP; chiral atropisomeric diphosphines
Settore CHIM/03 - Chimica Generale e Inorganica
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/717673
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