Self‐standing membranes consisting of inherently chiral electroactive oligomers: electrosynthesis, characterization and preliminary tests in potentiometric setups

Self‐standing chiral electroactive synthetic membranes are presented, prepared by oxidative electrooligomerization of a thiophene‐based "inherently chiral" electroactive monomer on indium tin oxide ITO or fluorine doped tin oxide FTO electrodes, followed by detachment of the electrodeposited thin films in aqueous solution. The membranes, possibly mesoporous, consist of a mixture of open and cyclic "inherently chiral" oligomers, i.e. in which both chirality and electroactivity originate from the same source, the main conjugated backbone featuring a tailored torsion; such a combination can afford outstanding chirality manifestations. The electrosynthesis conditions significantly modulate the oligomer distribution. Racemate films are compared to enantiopure ones. Circular dichroism confirms that (R)‐ or (S)‐ enantiopure films are obtained starting from the corresponding (R)‐ or (S)‐ enantiopure monomers. Reliable transmembrane potential readings are obtained in preliminary tests in ion‐selective electrode (ISE)‐like setups, consistent with those predicted considering the membrane features, a first step towards extension of the protocol to chiral experiments.