The rationale of this chapter is to illustrate how palladium salts and complexes as catalysts are important in the recent development of carbonylation reactions devoted to the synthesis of heterocyclic compounds. Carbonylative metal-catalyzed processes have proven to be a very powerful tool for the synthesis of heterocycles and a great number of reviews and books focusing or containing detailed descriptions on this argument have been published. Thus, this chapter does not present a complete historical coverage of the matter, but presents the most significant developments of the last 10 years. The emphasis is on novel and synthetic transformations of genuine value to organic chemists. Especially, this review will focus on carbonylative reactions involving oxidative addition of Pd(0) into Csp2-X bond (subchapter 1) and oxidative carbonylation reactions mediated by palladium(II) salts (subchapter 2)
Palladium-assisted synthesis of heterocycles via carbonylation reactions / E. Rossi - In: Modern carbonylation methods / A. Arcadi, C. Claver, C.S. Consorti, M. Diéguez, S. Doherty, J. Dupont, Z. Freixa, C. Godard, T. Kègel, J.G. Knught, L. Kollàr, M. Larhed, P.W.N.M. van Leeuwen, D. Morales-Morales, A. Nomoto, A. Ogawa, O. Pàmies, A. Ruiz, D. Selent, R. Skoda-Foldes, C.H. Smyth, F. Ungvàry, N. Ungvàry, J. Wannberg ; [a cura di] L. Kollàr. - Germany : Wiley-VCH, 2008. - ISBN 9783527318964. - pp. 321-362 [10.1002/9783527621545.ch13]
Palladium-assisted synthesis of heterocycles via carbonylation reactions
E. RossiPrimo
2008
Abstract
The rationale of this chapter is to illustrate how palladium salts and complexes as catalysts are important in the recent development of carbonylation reactions devoted to the synthesis of heterocyclic compounds. Carbonylative metal-catalyzed processes have proven to be a very powerful tool for the synthesis of heterocycles and a great number of reviews and books focusing or containing detailed descriptions on this argument have been published. Thus, this chapter does not present a complete historical coverage of the matter, but presents the most significant developments of the last 10 years. The emphasis is on novel and synthetic transformations of genuine value to organic chemists. Especially, this review will focus on carbonylative reactions involving oxidative addition of Pd(0) into Csp2-X bond (subchapter 1) and oxidative carbonylation reactions mediated by palladium(II) salts (subchapter 2)
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