We investigate the process of shear melting and resolidification of a colloidal glass, directly after loading (preyielding) and after a series of consecutive strain sweeps (postyielding). The postyielding glass shows a significant softening compared with the preyielding glass, together with the absence of history effects in successive shear melting protocols, indicating a reproducible process of fluidisation and resolidification into a glass state unaffected by residual stresses. However, a significant hysteresis characterizes strain sweeps with increasing or decreasing strain amplitude. The appearance of history and hysteresis effects coincides with the formation of a glass state, whereas it is not observed in the liquid. We can describe the onset of shear melting over a broad range of volume fractions and frequencies using a recently developed model which describes the yielding process in terms of loss of long-lived nearest neighbors.

A well defined glass state obtained by oscillatory shear / L. Pérez-Ocampo, A. Zaccone, M. Laurati. - In: JOURNAL OF RHEOLOGY. - ISSN 0148-6055. - 62:1(2018 Jan 08), pp. 197-207. [10.1122/1.5009199]

A well defined glass state obtained by oscillatory shear

A. Zaccone
Penultimo
;
2018

Abstract

We investigate the process of shear melting and resolidification of a colloidal glass, directly after loading (preyielding) and after a series of consecutive strain sweeps (postyielding). The postyielding glass shows a significant softening compared with the preyielding glass, together with the absence of history effects in successive shear melting protocols, indicating a reproducible process of fluidisation and resolidification into a glass state unaffected by residual stresses. However, a significant hysteresis characterizes strain sweeps with increasing or decreasing strain amplitude. The appearance of history and hysteresis effects coincides with the formation of a glass state, whereas it is not observed in the liquid. We can describe the onset of shear melting over a broad range of volume fractions and frequencies using a recently developed model which describes the yielding process in terms of loss of long-lived nearest neighbors.
Settore FIS/03 - Fisica della Materia
Settore FIS/02 - Fisica Teorica, Modelli e Metodi Matematici
8-gen-2018
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/609934
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