Hg{CH2C(O) Me}(2)] reacts with K[PtCl3(CH2LCH2)] (2 : 1 molar ratio) to give K[Pt-2{CH2C(O) Me}(6)(mu- Cl)(3)] ( 1); the intermediate [Pt{CH2C(O) Me} Cl-2(CH2=CH2)](-) has been detected in solution and isolated as a Me4N+ salt; the process occurs through successive normal and redox transmetallation reactions and an ab initio X-ray powder diffraction study of 1 has proven to be essential to establish its nature.
An unprecedented process involving normal and redox transmetallation reactions between Hg and Pt affording the unexpected K[Pt-2{CH2C(O)Me}(6)(mu-Cl)(3)] complex: the key role of X-ray powder diffraction in unravelling its nature and structure / J. Vicente, A. Arcas, J.M. Fernandez Hernandez, A. Sironi, N. Masciocchi. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 10(2005), pp. 1267-1269. [10.1039/b416261g]
An unprecedented process involving normal and redox transmetallation reactions between Hg and Pt affording the unexpected K[Pt-2{CH2C(O)Me}(6)(mu-Cl)(3)] complex: the key role of X-ray powder diffraction in unravelling its nature and structure
A. SironiPenultimo
;
2005
Abstract
Hg{CH2C(O) Me}(2)] reacts with K[PtCl3(CH2LCH2)] (2 : 1 molar ratio) to give K[Pt-2{CH2C(O) Me}(6)(mu- Cl)(3)] ( 1); the intermediate [Pt{CH2C(O) Me} Cl-2(CH2=CH2)](-) has been detected in solution and isolated as a Me4N+ salt; the process occurs through successive normal and redox transmetallation reactions and an ab initio X-ray powder diffraction study of 1 has proven to be essential to establish its nature.
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