Phtalates constitutes the 70 % of the overall plasticizer production. Despite their unique physicochemical properties, most of the esters of phthalic acid pose health concerns and lead the European Union to restrict their amount in plastic to a level below the 0.1 % by weight in June 2017. Toxic phthalates may be substituted by epoxidized soybean biodiesel (ESB). Although ESB are comparable to commercial bioplasticizers in terms of oxygen content, no information is available for the cost of a unit operation to produce ESB. In this work, we model the epoxidation reaction of soybean biodiesel and we simulate a unit operation that produces ESB. A Python script calls iteratively a PRO/II 9.3 simulation file that numerically solves the mass balances. A MATLAB 2017b script solves the kinetic equations. We estimate the operative and capital costs, and we identify the best techno-economic ESB production conditions for the explored range of reaction parameters.

Analysis of a bio-plasticizer production unit from biodiesel / F. Galli, D. Guzzetti, C. Pirola - In: 13th Conference on sustainable Development of Energy, Water and Environment Systems (SDEWES)[s.l] : Marko Ban et al., 2018. - pp. 1-10 (( Intervento presentato al 13. convegno Conference on sustainable Development of Energy, Water and Environment Systems tenutosi a Palermo nel 2018.

Analysis of a bio-plasticizer production unit from biodiesel

F. Galli;C. Pirola
2018

Abstract

Phtalates constitutes the 70 % of the overall plasticizer production. Despite their unique physicochemical properties, most of the esters of phthalic acid pose health concerns and lead the European Union to restrict their amount in plastic to a level below the 0.1 % by weight in June 2017. Toxic phthalates may be substituted by epoxidized soybean biodiesel (ESB). Although ESB are comparable to commercial bioplasticizers in terms of oxygen content, no information is available for the cost of a unit operation to produce ESB. In this work, we model the epoxidation reaction of soybean biodiesel and we simulate a unit operation that produces ESB. A Python script calls iteratively a PRO/II 9.3 simulation file that numerically solves the mass balances. A MATLAB 2017b script solves the kinetic equations. We estimate the operative and capital costs, and we identify the best techno-economic ESB production conditions for the explored range of reaction parameters.
Bioplasticizer; process design; PRO/II; economic optimization; unit operation simulation
Settore ING-IND/25 - Impianti Chimici
Settore CHIM/04 - Chimica Industriale
2018
Book Part (author)
File in questo prodotto:
File Dimensione Formato  
PAL2018_0404_M_v_01 (1).pdf

accesso riservato

Tipologia: Post-print, accepted manuscript ecc. (versione accettata dall'editore)
Dimensione 380.5 kB
Formato Adobe PDF
380.5 kB Adobe PDF   Visualizza/Apri   Richiedi una copia
Pubblicazioni consigliate

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/593905
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus ND
  • ???jsp.display-item.citation.isi??? ND
social impact