Hybrid mixed metal oxalates of general formula [M2III MII (C2 O4)6] [DAMS]4 · 2 DAMBA · 2 H2 O, where MIII = Rh, Fe, Cr; MII = Mn, Zn; DAMBA = para-dimethylaminobenzaldehyde and [DAMS+] = trans-4-(4-dimethylaminostyryl)-1-methylpyridinium, belong to a new family of multifunctional materials displaying both very high second harmonic generation (SHG) efficiency and tunable magnetic properties. Here we report on the preparation and magnetic characterization of the new NiII members of this family. Such new hybrid mixed metal oxalates are isostructural with the previously investigated containing ZnII and MnII, thus preserving the very high NLO efficiency but allowing further significant tuning of the magnetic properties. In particular the delocalization of NiII magnetic orbitals along the inorganic "stripes" of the crystalline network produces strong next-nearest-neighbor magnetic interactions, otherwise absent in the chains of compounds containing the MnII ions. Such interactions, when in the presence of magnetic MIII ions such as CrIII or FeIII, give rise to an interesting and complex magnetic behavior possibly due to an almost perfect compensation between nearest-neighbor and next-nearest-neighbor interactions along the chain.

Tuning the magnetic properties of a new family of hybrid mixed metal oxalates having 1D magnetic chains and layers of J aggregates of [DAMS+] producing superior SHG / E. Cariati, R. Macchi, E. Tordin, R. Ugo, L. Bogani, A. Caneschi, P. Macchi, N.P. Casati, A. Sironi. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - 361:14/15(2008), pp. 4004-4011.

Tuning the magnetic properties of a new family of hybrid mixed metal oxalates having 1D magnetic chains and layers of J aggregates of [DAMS+] producing superior SHG

E. Cariati
Primo
;
R. Macchi
Secondo
;
E. Tordin;R. Ugo;P. Macchi;N.P. Casati
Penultimo
;
A. Sironi
Ultimo
2008

Abstract

Hybrid mixed metal oxalates of general formula [M2III MII (C2 O4)6] [DAMS]4 · 2 DAMBA · 2 H2 O, where MIII = Rh, Fe, Cr; MII = Mn, Zn; DAMBA = para-dimethylaminobenzaldehyde and [DAMS+] = trans-4-(4-dimethylaminostyryl)-1-methylpyridinium, belong to a new family of multifunctional materials displaying both very high second harmonic generation (SHG) efficiency and tunable magnetic properties. Here we report on the preparation and magnetic characterization of the new NiII members of this family. Such new hybrid mixed metal oxalates are isostructural with the previously investigated containing ZnII and MnII, thus preserving the very high NLO efficiency but allowing further significant tuning of the magnetic properties. In particular the delocalization of NiII magnetic orbitals along the inorganic "stripes" of the crystalline network produces strong next-nearest-neighbor magnetic interactions, otherwise absent in the chains of compounds containing the MnII ions. Such interactions, when in the presence of magnetic MIII ions such as CrIII or FeIII, give rise to an interesting and complex magnetic behavior possibly due to an almost perfect compensation between nearest-neighbor and next-nearest-neighbor interactions along the chain.
Settore CHIM/03 - Chimica Generale e Inorganica
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2434/57259
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