The use of DAB dendrimers in halogen bonding-based crystal engineering is reported. The DAB-dendr-(NHC6F4I)(2)(2) self-assembles with (E)-1,2-bis-(4-pyridyl)-ethylene in a 1:2 supramolecular adduct, whose crystal lattice is composed of 5-fold interpenetrated sql networks, which is the highest degree for a square topology reported so far. The synthesis and coordination properties of higher generation dendrimers are also described, both in the liquid state and in solution.
Dendrimeric tectons in halogen bonding-based crystal engineering / P. Metrangolo, F. Meyer, T. Pilati, D.M. Proserpio, G. Resnati. - In: CRYSTAL GROWTH & DESIGN. - ISSN 1528-7483. - 8:2(2008), pp. 654-659. [10.1021/cg700870t]
Dendrimeric tectons in halogen bonding-based crystal engineering
D.M. ProserpioPenultimo
;
2008
Abstract
The use of DAB dendrimers in halogen bonding-based crystal engineering is reported. The DAB-dendr-(NHC6F4I)(2)(2) self-assembles with (E)-1,2-bis-(4-pyridyl)-ethylene in a 1:2 supramolecular adduct, whose crystal lattice is composed of 5-fold interpenetrated sql networks, which is the highest degree for a square topology reported so far. The synthesis and coordination properties of higher generation dendrimers are also described, both in the liquid state and in solution.
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