The effect on the second-order nonlinear optical properties of the nature of the pi-delocalized moiety in the position 5 of a 1,3-di(2-pyridyl)benzene cyclometallated to a platinum(II) center was investigated. The influence of the substitution of a double bond with a triple bond as bridge between a triphenylamino group and the cyclometallated phenyl ring was studied and turned out to be negligible. Remarkably, the novel easily-prepared platinum(II) complex with a cyclometallated 5-styryl-1,3-di(2-pyridyl)benzene is characterized by a good second-order NLO response, as determined in solution by the EFISH technique; it is a good candidate for application in photonics.
Design of cyclometallated 5-p-delocalized donor-1,3-di(2-pyridyl) benzene platinum(II) complexes with second-order nonlinear optical properties / N. Baggi, E. Garoni, A. Colombo, C. Dragonetti, S. Righetto, D. Roberto, J. Boixel, V. Guerchais, S. Fantacci. - In: POLYHEDRON. - ISSN 0277-5387. - 140(2018 Feb 08), pp. 74-77.
Design of cyclometallated 5-p-delocalized donor-1,3-di(2-pyridyl) benzene platinum(II) complexes with second-order nonlinear optical properties
N. Baggi;E. Garoni;A. Colombo
;C. Dragonetti;S. Righetto;D. Roberto;
2018
Abstract
The effect on the second-order nonlinear optical properties of the nature of the pi-delocalized moiety in the position 5 of a 1,3-di(2-pyridyl)benzene cyclometallated to a platinum(II) center was investigated. The influence of the substitution of a double bond with a triple bond as bridge between a triphenylamino group and the cyclometallated phenyl ring was studied and turned out to be negligible. Remarkably, the novel easily-prepared platinum(II) complex with a cyclometallated 5-styryl-1,3-di(2-pyridyl)benzene is characterized by a good second-order NLO response, as determined in solution by the EFISH technique; it is a good candidate for application in photonics.File | Dimensione | Formato | |
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