A novel cationic cyclometallated Ir(III) complex, namely [Ir(C^N-ppy-4-CH[dbnd]CHC6H4NEt2)2(N^N-bpy-CH[dbnd]CHC6H4NEt2)][PF6] (ppy = 2-phenylpyridine; bpy = 2,2′-bipyridine), was prepared and well characterized. Its good second-order NLO response, as determined in solution by the EFISH technique, and its interesting two-photon absorption activity, as measured by the Z-scan technique in the femtosecond case, make it a good candidate for application in photonics and biomedicine.
A novel multifunctional cyclometallated iridium(III) complex with interesting second-order nonlinear optical properties and two-photon absorption activity / A. Colombo, E. Garoni, C. Dragonetti, S. Righetto, D. Roberto, N. Baggi, M. Escadeillas, V. Guerchais, K. Kamada. - In: POLYHEDRON. - ISSN 0277-5387. - 140(2018 Feb 08), pp. 116-121.
|Titolo:||A novel multifunctional cyclometallated iridium(III) complex with interesting second-order nonlinear optical properties and two-photon absorption activity|
DRAGONETTI, CLAUDIA (Corresponding)
|Parole Chiave:||Cyclometallated iridium(III) complexes; EFISH; Second-order nonlinear optics; Two-photon absorption activity; Physical and Theoretical Chemistry; Inorganic Chemistry; Materials Chemistry; 2506; Metals and Alloys|
|Settore Scientifico Disciplinare:||Settore CHIM/03 - Chimica Generale e Inorganica|
|Data di pubblicazione:||8-feb-2018|
|Data ahead of print / Data di stampa:||16-dic-2017|
|Digital Object Identifier (DOI):||http://dx.doi.org/10.1016/j.poly.2017.12.009|
|Appare nelle tipologie:||01 - Articolo su periodico|