Reduction of suitably substituted organic nitro compounds by CO, catalyzed by different metal complexes, affords a variety of N-heterocyclic compounds. Carbon dioxide is the only stoichiometric byproduct. Several inter-molecular condensations have also been developed during the year in which a nitroarene and an alkene, diene or alkyne are reacted together to afford indoles, pyrroles, oxazines or allylic amines. This account focusses on the results obtained by our group in this field in the last 30Â years. A special attention is given to the more recently developed inter-molecular reactions.
The reduction of organic nitro compounds by carbon monoxide as an effective strategy for the synthesis of N-heterocyclic compounds: a personal account / F. Ferretti, D. Formenti, F. Ragaini. - In: RENDICONTI LINCEI. SCIENZE FISICHE E NATURALI. - ISSN 2037-4631. - 28:S1(2017 Jul), pp. 97-115.
|Titolo:||The reduction of organic nitro compounds by carbon monoxide as an effective strategy for the synthesis of N-heterocyclic compounds: a personal account|
FERRETTI, FRANCESCO (Primo)
RAGAINI, FABIO ATTILIO CIRILLO (Ultimo)
|Parole Chiave:||carbon monoxide; homogeneous catalysis; N-heterocycles; nitroarenes; palladium; 2300; agricultural and biological sciences (all); earth and planetary sciences (all)|
|Settore Scientifico Disciplinare:||Settore CHIM/03 - Chimica Generale e Inorganica|
Settore CHIM/06 - Chimica Organica
|Data di pubblicazione:||lug-2017|
|Digital Object Identifier (DOI):||http://dx.doi.org/10.1007/s12210-017-0601-7|
|Appare nelle tipologie:||01 - Articolo su periodico|