Low-cost, continuous, high-efficiency resolution technology is clearly needed for commercial-scale preparation of enantiomerically pure substances. Membrane technology, fortunately, fulfils this need very well because of its high efficiency, low energy usage, simplicity, convenience for up- and/or down-scaling, and continuous operability. Membrane-based chiral resolution can be achieved using either enantioselective or non-enantioselective membranes. The enantioselective membranes themselves can carry out chiral separation of enantiomers because they contain chiral recognition sites (1). Considering the outstanding enantioselection ability achieved with our inherently chiral surfaces (2) we have decided to synthesize by electrooligomerization inherently chiral membranes. These membranes were electrodeposited on FTO electrodes from the enanantiopure monomers of our inherently chiral forefather (BT2T4) dissolved in acetonitrile + tetrabutylammonium hexafluorophosphate 0.1 M as supporting electrolyte. The chiral membrane detachment is then obtained by dipping the FTO in deionized water. Preliminary tests have shown that they are electroactive with a perfectly specular CD spectra. We have also performed experiments by inserting the enantiopure membrane in a support normally used for ISE electrodes. References: 1. R. Xie, L.-Y. Chu, J.-G. Deng, Chem.Soc.Rev., 37 (2008) 1243–1263, 2. F. Sannicolò, S. Arnaboldi, T. Benincori, V. Bonometti, R. Cirilli, L. Dunsch, W. Kutner, G. Longhi, P. R. Mussini, M. Panigati, M. Pierini, S. Rizzo, Angew Chem. Int. Ed., 53 (2014) 2623-2627.
Artificial Inherently Chiral Electroactive Membranes / S. Arnaboldi, T. Benincori, F. Sannicolo', P.R. Mussini. ((Intervento presentato al 26. convegno Congresso Nazionale della Società Chimica Italiana tenutosi a Paestum nel 2017.
Artificial Inherently Chiral Electroactive Membranes
S. Arnaboldi
Primo
;F. Sannicolo'Penultimo
;P.R. MussiniUltimo
2017
Abstract
Low-cost, continuous, high-efficiency resolution technology is clearly needed for commercial-scale preparation of enantiomerically pure substances. Membrane technology, fortunately, fulfils this need very well because of its high efficiency, low energy usage, simplicity, convenience for up- and/or down-scaling, and continuous operability. Membrane-based chiral resolution can be achieved using either enantioselective or non-enantioselective membranes. The enantioselective membranes themselves can carry out chiral separation of enantiomers because they contain chiral recognition sites (1). Considering the outstanding enantioselection ability achieved with our inherently chiral surfaces (2) we have decided to synthesize by electrooligomerization inherently chiral membranes. These membranes were electrodeposited on FTO electrodes from the enanantiopure monomers of our inherently chiral forefather (BT2T4) dissolved in acetonitrile + tetrabutylammonium hexafluorophosphate 0.1 M as supporting electrolyte. The chiral membrane detachment is then obtained by dipping the FTO in deionized water. Preliminary tests have shown that they are electroactive with a perfectly specular CD spectra. We have also performed experiments by inserting the enantiopure membrane in a support normally used for ISE electrodes. References: 1. R. Xie, L.-Y. Chu, J.-G. Deng, Chem.Soc.Rev., 37 (2008) 1243–1263, 2. F. Sannicolò, S. Arnaboldi, T. Benincori, V. Bonometti, R. Cirilli, L. Dunsch, W. Kutner, G. Longhi, P. R. Mussini, M. Panigati, M. Pierini, S. Rizzo, Angew Chem. Int. Ed., 53 (2014) 2623-2627.File | Dimensione | Formato | |
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