We report the first example of a rod MOF in which the rod axes intersect. This suggests a new area of reticular chemistry in which helical rods that can be linked into frameworks are designed.
Two Exceptional Patterns of Helical Secondary Building Units Found in Metal-Organic Framework Structures / E.V. Alexandrov, A.V. Goltsev, M. O'Keeffe, D.M. Proserpio. - In: CRYSTAL GROWTH & DESIGN. - ISSN 1528-7483. - 17:6(2017), pp. 2941-2944.
Two Exceptional Patterns of Helical Secondary Building Units Found in Metal-Organic Framework Structures
D.M. ProserpioUltimo
2017
Abstract
We report the first example of a rod MOF in which the rod axes intersect. This suggests a new area of reticular chemistry in which helical rods that can be linked into frameworks are designed.
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Helix Rod MOFs paper_revised2.pdf
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