a detailed electrochemical and photophysical comparative study of three parallel series of phenyl, thienyl and furyl substituted ethylenes has been carried out, implemented by the computational calculation of selected terms. Relationships have been highlighted between molecular structure (number and type of aromatic rings) and important functional properties (in particular, electronic features and oligomerization ability). Interestingly, some of the studied heteroaryl-ethylenes show emission in the solid state displaying an aggregation-induced emission behavior.
A comparative study of electrochemical, spectroscopic and structural properties of phenyl, thienyl and furyl substituted ethylenes / L. Viglianti, F. Villafiorita Monteleone, C. Botta, P.R. Mussini, E. Ortoleva, S. Cauteruccio, E. Licandro, C. Baldoli. - In: CHEMISTRYSELECT. - ISSN 2365-6549. - 2:9(2017 Mar), pp. 2763-2773.
Titolo: | A comparative study of electrochemical, spectroscopic and structural properties of phenyl, thienyl and furyl substituted ethylenes |
Autori: | LICANDRO, EMANUELA (Penultimo) |
Parole Chiave: | alkenes; electrochemistry; electrooligomerization; heterocycles; solid state emission |
Settore Scientifico Disciplinare: | Settore CHIM/06 - Chimica Organica Settore CHIM/01 - Chimica Analitica Settore CHIM/02 - Chimica Fisica |
Data di pubblicazione: | mar-2017 |
Rivista: | |
Tipologia: | Article (author) |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1002/slct.201700109 |
Appare nelle tipologie: | 01 - Articolo su periodico |
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Manuscript Chem Select_accepted .pdf | Pre-print (manoscritto inviato all'editore) | Open Access Visualizza/Apri | ||
Viglianti_et_al-2017-ChemistrySelect.pdf | Publisher's version/PDF | Administrator Richiedi una copia | ||
slct201700109-sup-0001-misc_information.pdf | Supporting information | Altro | Administrator Richiedi una copia |