We report the design, synthesis, molecular optical properties, and solid state emissive behaviour of a series of novel compounds, which, similar to the archetypal AIE luminogen tetraphenylethene, are formed of a central olefin stator and decorated with either three or four rotors. These rotors, being either electron-rich substituted benzenes, or electron-withdrawing functional groups (esters, ketones, cyano groups) confer a “push–pull” character to the overall molecular structure. Building on both new and already published contributions, a comprehensive picture of the properties and the potential of these compounds is provided.
Structure-activity relationship for the solid state emission of a new family of "push-pull" pi-extended chromophores / A. Nitti, F. Villafiorita Monteleone, A. Pacini, C. Botta, T. Virgili, A. Forni, E. Cariati, M. Boiocchi, D. Pasini. - In: FARADAY DISCUSSIONS. - ISSN 1364-5498. - 196(2017), pp. 143-161.
Structure-activity relationship for the solid state emission of a new family of "push-pull" pi-extended chromophores
E. Cariati;
2017
Abstract
We report the design, synthesis, molecular optical properties, and solid state emissive behaviour of a series of novel compounds, which, similar to the archetypal AIE luminogen tetraphenylethene, are formed of a central olefin stator and decorated with either three or four rotors. These rotors, being either electron-rich substituted benzenes, or electron-withdrawing functional groups (esters, ketones, cyano groups) confer a “push–pull” character to the overall molecular structure. Building on both new and already published contributions, a comprehensive picture of the properties and the potential of these compounds is provided.File | Dimensione | Formato | |
---|---|---|---|
Submitted Faraday.pdf
accesso aperto
Tipologia:
Post-print, accepted manuscript ecc. (versione accettata dall'editore)
Dimensione
1.34 MB
Formato
Adobe PDF
|
1.34 MB | Adobe PDF | Visualizza/Apri |
c6fd00161k.pdf
accesso aperto
Tipologia:
Publisher's version/PDF
Dimensione
1.13 MB
Formato
Adobe PDF
|
1.13 MB | Adobe PDF | Visualizza/Apri |
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.