Non-metamict betafite, a pyrochlore-group mineral with general formula A2-mB2XO6Y(O,OH,F 1-n·pH2O and 2 Ti > Nb+Ta and U > 20% at the A site, has been found at Le Carcarelle, (Latium, Italy). It occurs within miarolitic cavities of a foid-bearing syenitic ejectum enclosed within the pyroclastic formation known as "ignimbrite C", which belongs to the main effusive phase of the Vico volcanic complex. The host rock is composed of K-feldspar, biotite, augitic clinopyroxene, magnetite and minor sodalite. Electron microprobe analyses gave the following crystal-chemical formula: (Ca 1.24Na0.17U0.49REE0.03Σ=1.93 (Ti1.05 Nb0.76Zr 0.14Fe0.04Ta0.01) Σ=2.00O6(O,OH). Compared with other occurrences reported in the mineralogical literature, betafite from Le Carcarelle is extremely enriched in U and depleted in Th. Due to its young age of formation (∼150 k.y.), this betafite sample is highly crystalline, thus allowing structure refinement of unheated material. Betafite from Le Carcarelle is cubic Fd3̄m, with a = 10.2637(13) Å, and V = 1081.21(35) Å3, and has a smaller A site (consistent with the higher U content), and a larger and more distorted B site (consistent with the higher Ti content) than calciobetafite from Campi Flegrei, Italy (Mazzi and Munno, 1983). Analysis of the atomic displacement parameters provides evidence for static disorder at the X site.
Non-metamict betafite from Le Carcarelle (Vico volcanic complex, Italy) : occurrence and crystal structure / F. Cámara, C.T. Williams, G. Della Ventura, R. Oberti, E. Caprilli. - In: MINERALOGICAL MAGAZINE. - ISSN 0026-461X. - 68:6(2004 Dec), pp. 939-950.
Non-metamict betafite from Le Carcarelle (Vico volcanic complex, Italy) : occurrence and crystal structure
F. Cámara
;
2004
Abstract
Non-metamict betafite, a pyrochlore-group mineral with general formula A2-mB2XO6Y(O,OH,F 1-n·pH2O and 2 Ti > Nb+Ta and U > 20% at the A site, has been found at Le Carcarelle, (Latium, Italy). It occurs within miarolitic cavities of a foid-bearing syenitic ejectum enclosed within the pyroclastic formation known as "ignimbrite C", which belongs to the main effusive phase of the Vico volcanic complex. The host rock is composed of K-feldspar, biotite, augitic clinopyroxene, magnetite and minor sodalite. Electron microprobe analyses gave the following crystal-chemical formula: (Ca 1.24Na0.17U0.49REE0.03Σ=1.93 (Ti1.05 Nb0.76Zr 0.14Fe0.04Ta0.01) Σ=2.00O6(O,OH). Compared with other occurrences reported in the mineralogical literature, betafite from Le Carcarelle is extremely enriched in U and depleted in Th. Due to its young age of formation (∼150 k.y.), this betafite sample is highly crystalline, thus allowing structure refinement of unheated material. Betafite from Le Carcarelle is cubic Fd3̄m, with a = 10.2637(13) Å, and V = 1081.21(35) Å3, and has a smaller A site (consistent with the higher U content), and a larger and more distorted B site (consistent with the higher Ti content) than calciobetafite from Campi Flegrei, Italy (Mazzi and Munno, 1983). Analysis of the atomic displacement parameters provides evidence for static disorder at the X site.File | Dimensione | Formato | |
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