A green, convenient and scalable one-pot two-enzyme method for the glucosylation of arylalkyl alcohols has been developed. The reaction scheme is based on a transrutinosylation catalyzed by a rutinosidase from A. niger using the cheap commercially available natural flavonoid rutin as glycosyl donor, followed by a selective ‘trimming’ of the rutinoside unit catalyzed by a rhamnosidase from A. terreus.
Synthesis, Laccase-catalyzed Dimerization and Enzymatic Elaboration of Glycosylated Phenylpropenols / I. Bassanini, P. Gavezzotti, D. Monti, J. Krejzova, V. Křen, S. Riva. ((Intervento presentato al convegno OxiZymes tenutosi a Wageningen nel 2016.
Synthesis, Laccase-catalyzed Dimerization and Enzymatic Elaboration of Glycosylated Phenylpropenols
I. Bassanini
;S. Riva
2016
Abstract
A green, convenient and scalable one-pot two-enzyme method for the glucosylation of arylalkyl alcohols has been developed. The reaction scheme is based on a transrutinosylation catalyzed by a rutinosidase from A. niger using the cheap commercially available natural flavonoid rutin as glycosyl donor, followed by a selective ‘trimming’ of the rutinoside unit catalyzed by a rhamnosidase from A. terreus.
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