The reactions of M-II sulfates (M = Zn, Cd) with the flexible ligand 1,4-bis(imidazol-1-ylmethyl)benzene (bix) yield the novel interesting coordination networks [M-2(bix)(3)(SO4)(2)], containing 1D polymeric motifs of alternating rings and rods, which show extended rotaxane-like mechanical links producing 2D sheets via unprecedented parallel (M = Zn) or inclined (M = Cd) interlacing modes of the chains.
Parallel and inclined (1D -> 2D) interlacing modes in new polyrotaxane frameworks [M-2(bix)(3)(SO4)(2)] [M = Zn(II), Cd(II); Bix=1,4-bis(imidazol-1-ylmethyl)benzene] / L. Carlucci, G. Ciani, D.M. Proserpio. - In: CRYSTAL GROWTH & DESIGN. - ISSN 1528-7483. - 5:1(2005), pp. 37-39.
Parallel and inclined (1D -> 2D) interlacing modes in new polyrotaxane frameworks [M-2(bix)(3)(SO4)(2)] [M = Zn(II), Cd(II); Bix=1,4-bis(imidazol-1-ylmethyl)benzene]
L. CarlucciPrimo
;G. CianiSecondo
;D.M. ProserpioUltimo
2005
Abstract
The reactions of M-II sulfates (M = Zn, Cd) with the flexible ligand 1,4-bis(imidazol-1-ylmethyl)benzene (bix) yield the novel interesting coordination networks [M-2(bix)(3)(SO4)(2)], containing 1D polymeric motifs of alternating rings and rods, which show extended rotaxane-like mechanical links producing 2D sheets via unprecedented parallel (M = Zn) or inclined (M = Cd) interlacing modes of the chains.
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