Phased out: A combination of electrochemical and optical techniques is used to study the interaction of hydrogen with palladium nanoclusters. Hydrogen pressure-composition isotherms reveal the reduced presence of the β phase in palladium nanoclusters. Hydrogen extraction transients relate the reduced miscibility gap to a core-shell phase transformation in the palladium nanoclusters (see picture).
Inhomogeneous phase transition upon hydrogenation of nanocluster Pd films / M. Di Vece, J.J. Kelly, P. Lievens. - In: CHEMPHYSCHEM. - ISSN 1439-4235. - 10:3(2009), pp. 512-515.
Inhomogeneous phase transition upon hydrogenation of nanocluster Pd films
M. Di Vece
;
2009
Abstract
Phased out: A combination of electrochemical and optical techniques is used to study the interaction of hydrogen with palladium nanoclusters. Hydrogen pressure-composition isotherms reveal the reduced presence of the β phase in palladium nanoclusters. Hydrogen extraction transients relate the reduced miscibility gap to a core-shell phase transformation in the palladium nanoclusters (see picture).
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