Nanoparticles on carbon nanotubes can be used as a high surface area catalyst or as a means to produce well-defined particles. In this study, cobalt nanoparticles were formed on xxsingle-walled carbon nanotubes during hydrogen exposure at an elevated temperature. The average particle size increased as a function of reaction time ranging from 1.5 to 40 nm, indicating hydrogen-induced Ostwald ripening which is remarkable for a nonhydrogen-absorbing material. Mass abundances and cobalt shells were observed which possibly contained hydrogen. The combination of large surface area, high atomic mobility, and hydrogen-induced Ostwald ripening resulted in a novel method to prepare various cobalt nanoparticle shapes and sizes.
Hydrogen-induced Ostwald ripening of cobalt nanoparticles on carbon nanotubes / M. Di Vece, C. Zoican-Loebick, L.D. Pfefferle. - In: JOURNAL OF NANOPARTICLE RESEARCH. - ISSN 1388-0764. - 16:2(2014), pp. 2234.1-2234.7. [10.1007/s11051-013-2234-9]
Hydrogen-induced Ostwald ripening of cobalt nanoparticles on carbon nanotubes
M. Di VecePrimo
;
2014
Abstract
Nanoparticles on carbon nanotubes can be used as a high surface area catalyst or as a means to produce well-defined particles. In this study, cobalt nanoparticles were formed on xxsingle-walled carbon nanotubes during hydrogen exposure at an elevated temperature. The average particle size increased as a function of reaction time ranging from 1.5 to 40 nm, indicating hydrogen-induced Ostwald ripening which is remarkable for a nonhydrogen-absorbing material. Mass abundances and cobalt shells were observed which possibly contained hydrogen. The combination of large surface area, high atomic mobility, and hydrogen-induced Ostwald ripening resulted in a novel method to prepare various cobalt nanoparticle shapes and sizes.Pubblicazioni consigliate
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