We disclose two unprecedented complexes built with a central dithienylethene photochrome connecting two cyclometalated Pt(ii) moieties either on the reactive carbon atoms or on the lateral non-reactive carbon atoms of the photochrome. The two systems show vastly different properties that are rationalised thanks to quantum-chemical calculations.
Contrasted photochromic and luminescent properties in dinuclear Pt(II) complexes linked through a central dithienylethene unit / J. Boixel, Y. Zhu, H. Le Bozec, M.A. Benmensour, A. Boucekkine, K.M. Wong, A. Colombo, D. Roberto, V. Guerchais, D. Jacquemin. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 52:63(2016), pp. 9833-9836. [10.1039/c6cc03431d]
Contrasted photochromic and luminescent properties in dinuclear Pt(II) complexes linked through a central dithienylethene unit
A. Colombo;D. Roberto;
2016
Abstract
We disclose two unprecedented complexes built with a central dithienylethene photochrome connecting two cyclometalated Pt(ii) moieties either on the reactive carbon atoms or on the lateral non-reactive carbon atoms of the photochrome. The two systems show vastly different properties that are rationalised thanks to quantum-chemical calculations.
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