Orthorhombic edingtonite has been found coexisting with tetragonal edingtonite in a specimen from Ice River, British Columbia, Canada. We report data on the composition and crystal structure of the orthorhombic sample. Lattice parameters are: a = 9.5341(6), b = 9.6446(6), c = 6.5108(7) Å, V = 598.68(8) Å3. The crystal structure was refined in space group P 21212 to R1 = 1.8% using 879 observed reflections. For the first time, evidence for splitting of the extra-framework Ba site in two different sites (Ba1, Ba2), ∼0.37 Å apart, is demonstrated. A comparison with the published crystal structures of tetragonal and orthorhombic edingtonite is made. The present result supports the suggestion that the two edingtonite phases are a consequence of different nucleation phenomena and not different physicochemical conditions.
New insight into the crystal structure of orthorhombic edingtonite: evidence for a split Ba site / G.D. Gatta, T.B. Ballaran. - In: MINERALOGICAL MAGAZINE. - ISSN 0026-461X. - 68:1(2004), pp. 167-175.
New insight into the crystal structure of orthorhombic edingtonite: evidence for a split Ba site
G.D. Gatta;
2004
Abstract
Orthorhombic edingtonite has been found coexisting with tetragonal edingtonite in a specimen from Ice River, British Columbia, Canada. We report data on the composition and crystal structure of the orthorhombic sample. Lattice parameters are: a = 9.5341(6), b = 9.6446(6), c = 6.5108(7) Å, V = 598.68(8) Å3. The crystal structure was refined in space group P 21212 to R1 = 1.8% using 879 observed reflections. For the first time, evidence for splitting of the extra-framework Ba site in two different sites (Ba1, Ba2), ∼0.37 Å apart, is demonstrated. A comparison with the published crystal structures of tetragonal and orthorhombic edingtonite is made. The present result supports the suggestion that the two edingtonite phases are a consequence of different nucleation phenomena and not different physicochemical conditions.File | Dimensione | Formato | |
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