We have measured the rotational tunneling spectrum of a Cu-ZSM-5 zeolite after loading with H2, by means of inelastic incoherent neutron scattering. The peaks at ±0.80 and ±1.73 cm-1 unambiguously demonstrate the formation of a strongly bound Cu(2-H2) complex.
Observation of Exceptionally Strong Binding of Molecular Hydrogen in a Porous Material: Formation of an eta2-H2 Complex in a Cu-Exchanged ZSM-5 Zeolite / P. Georgiev, A. Albinati, B.L. Mojet, J. Ollivier, J. Eckert. - In: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. - ISSN 0002-7863. - 129:26(2007), pp. 8086-8087.
Observation of Exceptionally Strong Binding of Molecular Hydrogen in a Porous Material: Formation of an eta2-H2 Complex in a Cu-Exchanged ZSM-5 Zeolite
P. GeorgievPrimo
;A. AlbinatiSecondo
;
2007
Abstract
We have measured the rotational tunneling spectrum of a Cu-ZSM-5 zeolite after loading with H2, by means of inelastic incoherent neutron scattering. The peaks at ±0.80 and ±1.73 cm-1 unambiguously demonstrate the formation of a strongly bound Cu(2-H2) complex.
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