The experimental re-investigation of a reported synthesis of a macrocyclic pseudopeptide promoted by bis(tetrabutylammonium) terephthalate allowed us to elucidate the nature of the non-bonding interactions between the reagents and the template; while the involvement of aromatic–aromatic interactions could be ruled out, the relevance of the role of the carboxylate ion was confirmed.
An experimental re-investigation of the role of aromatic-aromatic interactions in a templated synthesis of a macrocyclic pseudopeptide / G. Dell’Anna, M. Benaglia, L. Raimondi, F. Cozzi. - In: ORGANIC & BIOMOLECULAR CHEMISTRY. - ISSN 1477-0520. - 5:14(2007), pp. 2205-2206.
An experimental re-investigation of the role of aromatic-aromatic interactions in a templated synthesis of a macrocyclic pseudopeptide
G. Dell’AnnaPrimo
;M. BenagliaSecondo
;L. RaimondiPenultimo
;F. CozziUltimo
2007
Abstract
The experimental re-investigation of a reported synthesis of a macrocyclic pseudopeptide promoted by bis(tetrabutylammonium) terephthalate allowed us to elucidate the nature of the non-bonding interactions between the reagents and the template; while the involvement of aromatic–aromatic interactions could be ruled out, the relevance of the role of the carboxylate ion was confirmed.
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