Recently developed organocatalytic stereoselective transformations will be presented, including reactions of nitroacrylates, synthesis of chiral and trifluoromethyl amines, direct catalytic thioester aldol reactions; reaction mechanisms and a possible rationalization of the stereochemical outcome will be also discussed. Some of the same transformations have been performed in catalytic reactors, in flow mode: recent developments will be presented, highlighting also the possibility to perform organocatalytic reactions in microreactors.
Catalytic reactions in batch and under continuous-flow conditions / M. Benaglia. ((Intervento presentato al convegno Seminars for PhD school at the university La Sorbonne, Paris tenutosi a Paris nel 2016.
Catalytic reactions in batch and under continuous-flow conditions
M. Benaglia
2015
Abstract
Recently developed organocatalytic stereoselective transformations will be presented, including reactions of nitroacrylates, synthesis of chiral and trifluoromethyl amines, direct catalytic thioester aldol reactions; reaction mechanisms and a possible rationalization of the stereochemical outcome will be also discussed. Some of the same transformations have been performed in catalytic reactors, in flow mode: recent developments will be presented, highlighting also the possibility to perform organocatalytic reactions in microreactors.
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